Medizinische Universität Graz - Research portal
Selected Publication:
SHR Neuro Cancer Cardio Lipid Metab Microb
Filace, F; Sanchez-Murcia, PA; Sucunza, D; Perez-Redondo, A; Alvarez-Builla, J; Gago, F; Burgos, C.
Silyl Assistance in the Intramolecular Addition of Pyridyl Radicals onto Pyridines and Quinolines
EUR J ORG CHEM. 2016; 2016(10): 1891-1896.
Doi: 10.1002/ejoc.201600170
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- Co-authors Med Uni Graz
- Sánchez Murcia Pedro Alejandro
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- Abstract:
- The first example of a stable acylazinium salt obtained by an intramolecular acylpyridine-centered radical attack on azine nitrogen atoms is reported. Depending on the relative position of the bromo substituent on the attacking amino-pyridine ring, it is possible to obtain selectively either the N-attack product or a different C-attack derivative. A rationale for this pathway selectivity was obtained from quantum mechanical calculations.
- Find related publications in this database (Keywords)
- Radical reactions
- Density functional calculations
- Nitrogen heterocycles
- Silanes