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Gruber, D; Domiaty, U; Iskra, K; Dinev, S; Windholz, L.
Production of the NaHg molecule by reactive three-body collisions following energy-transferring processes of laser-excited Na(3 P-2) atoms
J PHYS CHEM-US. 1996; 100(17): 7078-7084. Doi: 10.1021/jp9531671
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Co-authors Med Uni Graz: Reiter Ursula
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Abstract:: We report on the production of the NaHg molecule via resonant excitation of the sodium D-lines following energy-pooling collisions of laser-excited Na(3 P-2) atoms. In addition to the chemiluminescence on the red NaHg(II1/2-X(1/2)) band system, we observed emission on the blue-band system. Production mechanisms as well as the dependence on particle density and excitation laser intensity are discussed, and the rate coefficients are determined.